Dichlorido[2,2′-(1,10-phenanthrolin-2-ylimino)diethanol]cadmium(II)
نویسندگان
چکیده
In the title complex, [CdCl(2)(C(16)H(17)N(3)O(2))], the metal atom exhibits a distorted trigonal-bipyramidal coordination geometry. O-H⋯O and O-H⋯Cl hydrogen bonds involving hydr-oxy groups and one of coordinated Cl atoms link complexes in the crystal packing. There is a π-π stacking inter-action between adjacent 1,10-phenanthroline rings, with a distance of 3.675 (2) Å between the centroids of the pyridine and benzene rings.
منابع مشابه
Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II)
In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal-bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short inter-molecular distances [3.627 (4)-3.671 (4) Å] between the centroids of the six- and five-membered Cd-containing rings suggest the exis...
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In the title compound, C(16)H(17)N(3)O(2), symmetry-related mol-ecules are linked into one-dimensional chains along the a axis by a combination of inter-molecular O-H⋯N and O-H⋯O hydrogen bonds and weak π-π stacking inter-actions with a centroid-centroid distance of 3.5494 (12) Å.
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In the title mononuclear complex, [CuCl(2)(C(17)H(11)N(3)O)], the Cu(II) ion is in a distorted square-pyramidal coordination environment. The crystal structure is stabilized by various π-π stacking inter-actions in which the benzene ring, a pyridine ring and the five-membered CuN(2)C(2) ring are involved. The centroid-centroid distances range from 3.5631 (15) to 3.5666 (16) Å.
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The title compound, [Ru(C(10)H(8)N(2))(2)(C(13)H(7)N(3)S)](PF(6))(2)·CH(3)CN, was synthesized by the reaction of thio-phosgene and bis-(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis-(hexa-fluoridophosphate). The Ru(II) atom adopts a slightly distorted octa-hedral RuN(6) coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline liga...
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